The viability of the conductometric titration of Ag + in aqueous medium with the thioacetamide was demonstrated. The relative error was 0.12%. Initially, the stability of thioacetamide in aqueous solution was confirmed. Analyzes carried out for 5 weeks at one week intervals showed no change in concentration in a thioacetamide solution. In order to obtain better precision in the determinations, the different titrant and titrated concentrations were used. The lowest relative error (0.12%) occurred with N solution of thioacetamide and 0.01 N solution of silver nitrate.